Synthesis of a lithium-cyclopentadienide complex by addition of LiNTf2 to a zwitterionic fulvalene.
نویسندگان
چکیده
The synthesis of a η5-coordinated LiCp complex by simple addition of a Li-salt in benzene is presented. A strongly zwitterionic fulvalene serves as the Cp-precursor. Evidence for the coordination of Li+ was obtained by the characterisitic 7Li NMR chemical shifts, variable temperature experiments in solution and by X-ray structure analysis in the solid state.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 46 1 شماره
صفحات -
تاریخ انتشار 2016